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舒兴中(教授)★

【来源:兰州大学化学化工学院 | 发布日期:2016-12-07 】     【选择字号:
姓 名
舒兴中
所属部门
有机化学第六研究所
职 称
教授
导师类别
博士生导师
研究方向
高性能均相、多相金属催化剂,(不对称)催化和反应机理
联系方式

舒兴中,兰州大学“萃英学者”特聘教授,博士生导师,入选第十二批国家“千人计划”青年人才。1982年生于浙江衢州。于2010年6月毕业于兰州大学并取得博士学位,师从梁永民教授;之后在威斯康辛大学麦迪逊分校从事博士后研究,师从Weiping Tang教授;并于2012年7月进入加州大学伯克利分校和劳伦斯伯克利国家实验室从事博士后研究,师从著名有机化学家F. Dean Toste教授和材料学家Paul Alivisatos教授;于2015年起在兰州大学化学化工学院、功能有机分子化学国家重点实验室从事教学科研工作。

研究以绿色合成为向导,通过开展有机合成方法学研究,探索解决环境和能源相关问题的新方法、新思路。主要包括:1)新型廉价金属催化剂的设计、制备和催化活性研究;2)高性能多相催化剂的开发及其催化性能研究; 3)以生物能源有效利用为基础的反应方法学研究。迄今为止,已在Chem. Soc. Rev.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed. 、NanoLett.等国际著名刊物上发表论文三十余篇,他引800余次, H因子19。成果被Synfacts、Organic Chemistry Portal等多家专业媒体报道。曾获第六届中国青少年科技创新奖、中国科学院奖学金和宝钢教育奖学金等多个奖项。是多家国际一流期刊的应邀审稿人,美国化学会会员。


    近期代表性论文: 

[16] Xing-ZhongShu, Son C. Nguyen, Ying He, Fadekemi Oba, Qiao Zhang, Christian Canlas, Gabor A. Somorjai*, A. Paul Alivisatos*, F. Dean Toste*, “Silica-Supported Cationic Gold(I) Complexes as Heterogeneous Catalysts for Regio- and EnantioselectiveLactonization Reactions”, J. Am. Chem. Soc., 2015, 137, 7083.

[15] Xing-zhong Shu, Miao Zhang, Ying He, Heinz, Frei*, F. Dean Toste*, “Dual Visible Light    Photoredox and Gold-catalyzed ArylativeRing Expansion”, J. Am. Chem. Soc. 2014, 136, 5844.

[14] Elad Gross, Xing-Zhong Shu, SelimAlayoglu, Hans A. Bechtel, Michael C. Martin, F. Dean Toste,* Gabor A. Somorjai*, “In situ IR and X?ray High Spatial-resolution MicrospectroscopyMeasurements of Multistep Organic Transformation in Flow MicroreactorCatalyzed by Au Nanoclusters”, J. Am. Chem. Soc., 2014, 136, 3624.

[13] Qiao Zhang, Xing-Zhong Shu, J. Matthew Lucas,F. Dean Toste*, Gabor A. Somorjai*, A. Paul Alivisatos*, “Inorganic Micelle as an Efficient and Recyclable Micellar Catalyst”, NanoLett. 2014,14, 379.

[12] Xing-zhong Shu, Casi M. Schienebeck, Wangze Song, Ilia A. Guzei, and Weiping Tang*, “Transfer of Chirality in Rhodium-Catalyzed Intramolecular (5+2) Cycloaddition of 3-Acyloxy-1,4-enyne (ACE) and Alkyne: Enantioselective Synthesis of Bicyclo[5.3.0]decatrienes”, Angew. Chem. Int. Ed.2013, 52, 13601.

[11] Xiufang Xu*, Peng Liu, Xing-Zhong Shu; Weiping Tang*; Houk, K. N.*, “Rh-Catalyzed (5+2) Cycloadditions of 3-Acyloxy-1,4-enynes and Alkynes: Computational Study of Mechanism, Reactivity, and Regioselectivity”, J. Am. Chem. Soc., 2013, 135, 9271.

[10] Xing-Zhong Shu, Dongxu Shu, Casi M. Schienebeck and Weiping Tang*, “Rhodium-catalyzed AcyloxyMigration of PropargylicEsters in Cycloadditions, Inspiration from the Recent "Gold Rush"”, Chem. Soc. Rev.2012, 41, 7698.

[9] Xing-Zhong Shu, Xiaoxun Li, Dongxu Shu, Suyu Huang, Casi Mae Schienebeck, Xin Zhou, Patrick J. Robichaux, Weiping Tang, “Rhodium-Catalyzed Intra- and Intermolecular 5+2 Cycloaddition of 3-Acyloxy-1,4-enyne and Alkyne with Concomitant 1,2-Acyloxy Migration”, J. Am. Chem. Soc., 2012, 134, 5211.

[8] Xing-Zhong Shu, Suyu Huang, Dongxu Shu, Ilia A. Guzei, Weiping Tang*, “Interception of a Rautenstrauch Intermediate by Alkynes for 5+2 Cycloaddition: Rhodium-Catalyzed Cycloisomerization of 3-Acyloxy-4-ene-1,9-diynes to Bicyclo 5.3.0 decatrienes”, Angew. Chem. Int. Ed.2011, 50, 8153.

[7] Xing-Zhong Shu, Yan-Fang Yang, Xiao-Feng Xia, Ke-Gong Ji, Xue-Yuan Liu, Yong-Min Liang*, “Platinum-catalyzed Cross-dehydrogenativeCoupling Reaction in the Absence of Oxidant”, Org. Biomol. Chem.2010, 8, 4077.

[6] Xing-Zhong Shu, Xiao-Feng Xia, Yan-Fang Yang, Ke-Gong Ji, Xue-Yuan Liu, Yong-Min Liang*, “Selective Functionalization of Sp(3) C-H Bonds Adjacent to Nitrogen Using (Diacetoxyiodo)benzene (DIB)”, J. Org. Chem. 2009, 74, 7464.

[5] Xing-Zhong Shu, Shu-Chun Zhao, Ke-Gong Ji, Zhao-Jing Zheng, Xue-Yuan Liu, Yong-Min Liang*, “Platinum-Catalyzed Cyclization of o-Alkynyl(oxo)benzenes with Alkenes by 1,2-Migration of Benzene: Synthesis of 8-Oxabicyclo 3.2.1 octane Derivatives”, Eur. J. Org. Chem. 2009, 117.

[4] Xing-Zhong Shu, Ke-Gong Ji, Shu-Chun Zhao, Zhao-Jing Zheng, Jing Chen, Li Lu, Xue-Yuan Liu, Yong-Min Liang*, “Synthesis of Naphthalenyl Acetate by Platinum-Catalyzed 1,5-Sigmatropic Hydrogen Shift of Propargylic Esters”, Chem. Eur. J. 2008, 14, 10556.

[3]Xing-Zhong Shu, Xue-Yuan Liu, Ke-Gong Ji, Hui-Quan Xiao, Yong-Min Liang*, “Au-catalyzed Tandem Cyclization/1,2 -alkyl Migration Reaction of Epoxy Alkynes: Synthesis of Spiropyranones”, Chem. Eur. J.2008, 14, 5282. 

[2] Xing-Zhong Shu, Xue-Yuan Liu, Hui-Quan Xiao, Ke-Gong Ji, Li-Na Guo, Yong-Min Liang*, “Tandem Gold(III)-catalyzed Amination-intramolecular HydroaminationReactions of 1-En-4-yn-3-ols with Sulfonamides: Efficient Approach to Highly Substituted Pyrroles”, Adv. Synth. Catal. 2008, 350, 243.

[1] Xing-Zhong Shu, Xue-Yuan Liu, Hui-Quan Xiao, Ke-Gong Ji, Li-Na Guo, Chen-Ze Qi, Yong-Min Liang*, “Gold-catalyzed Tandem Cycloisomerization of Alkynyloxiranes with Nucleophiles: An Efficient Approach to 2,5-Disubstituted Furans”, Adv. Synth. Catal. 2007, 349, 2493.