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许鹏飞 (教授)★

【来源:兰州大学化学化工学院 | 发布日期:2016-12-07 】     【选择字号:
姓  名
许鹏飞
所属部门
有机化学第六研究所
职  称
教授
导师类别
博士生导师
研究方向
不对称合成,不对称催化反应及天然产物全合成
联系方式
0931-8912281,0931-8912374(办) xupf@lzu.edu.cn

教育背景、工作经历

2015-至今             兰州大学萃英学院执行院长

2009-2015             兰州大学教务处处长

2003-至今             兰州大学化学化工学院、功能有机分子化学国家重点实验室,教授

2003-2004             日本名古屋大学物质材料科学国际研究中心(K. Tatsumi合作教授),访问教授

1999-2001             台湾中兴大学,博士后(陆大荣教授)

1996-1998             兰州大学,理学博士(张自义教授)

1992-1994             兰州大学,理学硕士(吴绍祖教授)

1983-1987             兰州大学,化学系有机化学专业,理学学士(李瑜教授)

 

·         荣誉奖励

2016兰州大学国华杰出学者奖

2014全国宝钢优秀教师奖;

2014   甘肃省科技进步一等奖(第一完成人);

2013   兰州大学师德标兵,甘肃省陇原师德先进个人称号;

2012   金川集团科技进步一等奖,国务院政府特殊津贴;

2010   甘肃省自然科学一等奖(第一完成人);

2009   入选甘肃省领军人才,Thieme Chemistry Journal Award

2005   入选教育部新世纪优秀人才支持计划、甘肃省“555”创新人才;

2002第九届甘肃省青年教师成才奖,甘肃省科技进步三等奖两项。

 

·         研究兴趣

1)α-氨基酸的不对称合成及方法研究;

2)有机小分子催化的不对称串联反应的研究;

3)天然产物结构导向的有机小分子催化反应的研究;

4)可见光催化的有机反应研究;

5) 新型可见光催化剂的设计与应用;

6)新型浮选剂的研发。

 

·         代表成果

1.         “Asymmetric Catalytic Cascade Reactions for Constructing Diverse Scaffolds and Complex Molecules”. Wang, Y.; Lu, H.;Xu, P.-F. *Acc. Chem. Res.2015, 48, 1832.

2.         “Synthesis of a-Amino Acids Based on Chiral Tricycloiminolactone Derived from Natural (+)-Camphor”. Luo, Y.-C.; Zhang, H.-H.; Wang, Y.;Xu, P.-F.*Acc. Chem. Res.2010, 43, 1317.

3.         “Rationally Designed Multifunctional Supramolecular Iminium Catalysis: Direct Vinylogous Michael Addition of Unmodified Linear Dienol Substrates”.Gu,Y.; Wang,Y.; Yu,T.-Y.; Liang,Y.-M.;* Xu, P.-F.*Angew. Chem., Int. Ed.2014, 53, 14128.

4.         “Hydrogen-Bond-Mediated Supramolecular Iminium Ion Catalysis”.Wang,Y.; Yu,T.-Y.; Zhang,H.-B.; Luo,Y.-C;Xu, P.-F.* Angew. Chem., Int. Ed.2012, 51, 12339.

5.         “Asymmetric Organocatalytic Relay Cascades: Catalyst-Controlled Stereoisomer Selection in the Synthesis of Functionalized Cyclohexanes”.Wang,Y.; Han,R.-G.; Zhao,Y.-L.; Yang,S.; Dixon,D. J.;Xu, P.-F.*Angew. Chem., Int. Ed.2009, 48, 9834.

6.         “Catalytic Cascade Reactions”.Xu, P.-F., Wang, W., Eds.; John Wiley & Sons: Canada, 2014.

7.         “Iridium(1+),Bis(acetonitrile)bis[2-[5-(1,1-dimethylethyl)-2-benzothiazolyl-kN3]phenyl-kC]-,(OC-6-13-Λ)Hexafluorophosphate(1-) (1:1)”. Xu, G.-Q.; Liang, H.; Xu, P.-F.*Encyclopedia of reagents for Organic Synthesis [Online], John Wiley & Sons Ltd., 2017.

8.         “N?Heterocyclic Carbene-Catalyzed Atom-Economical and Enantioselective Construction of the C?S Bond: Asymmetric Synthesis of Functionalized Thiochromans”.Lu, H.; Zhang, J.-L.; Liu, J.-Y.; Li, H.-Y.;Xu, P.-F.*ACS Catal.2017, 7, 7797.

9.         “3,4,5-Trimethylphenol and Lewis Acid Dual-Catalyzed Cascade Ring-Opening/Cyclization: Direct Synthesis of Naphthalenes”.Ma, H.; Hu, X.-Q.;* Luo, Y.-C.;Xu, P.-F.*Org. Lett.2017, 19, 6666.

10.     “Visible-Light-Induced Aza-Pinacol Rearrangement: Ring Expansion of Alkylidenecyclopropanes”.Liu, W.-D.; Xu, G.-Q.; Hu, X.-Q.;Xu, P.-F.*Org. Lett.2017, 19,6291.

11.     “Highly Enantioselective Construction of Hajos-Wiechert Ketone Skeletons via an Organocatalytic Vinylogous Michael/Stetter Relay Sequence”. Jia, Z.-L.; Wang, Y.; Zhao, C.-G.; Zhang, X.-H.;Xu, P.-F.*Org. Lett.2017, 19, 2130.

12.     “Quaternary Carbon Center Forming Formal [3+3] Cycloaddition Reaction via Bifunctional Catalysis: Asymmetric Synthesis of Spirocyclohexene Pyrazolones”. Liu, J.-Y.; Zhao, J.; Zhang, J.-L.;Xu, P.-F.*Org. Lett.2017, 19, 1846.

13.     “Synthesis of Fused Pyran Derivatives via Visible-Light-Induced Cascade Cyclization of 1,7-Enynes with Acyl Chlorides”. Li, C.-G.; Xu,G.-Q;Xu, P.-F.*Org. Lett.2017, 19, 512.

14.     “Rh(II) Catalyzed High Order Cycloadditions of 8-Azaheptafulvenes with N-Sulfonyl 1,2,3-Triazloes or α-Oxo Diazocompounds”. Chen, W.; Bai, Y.-L.; Luo, Y.-C.;Xu, P.-F.*Org. Lett.2017, 19, 364.

15.     “Lewis acid catalyzed diastereoselective [3+4]-annulation of donor-acceptor cyclopropanes with anthranils: synthesis of tetrahydro-1-benzazepine derivatives”.Wang, Z.-H.; Zhang, H.-H.;* Wang, D.-M.;Xu, P.-F.; Luo, Y.-C.* Chem.Commun.2017, 53, 8521.

16.     “Kinetic resolution via supramolecular iminium catalysis: multiactivation enables the asymmetric synthesis of beta-aryl substituted aldehydes and densely functionalized cyclohexanes”. Jia, Z.-L.; Wang, Y.;Xu, G.-Q.;Xu, P.-F.*Chem.Commun.2017, 53, 4938.

17.     “Metal-Free, Visible-Light-Promoted Synthesis of 3-Phosphorylated Coumarins via Radical C?P/C?C Bond Formation”.Liu, D.; Chen, J.-Q.; Wang, X.-Z.;Xu, P.-F.*Adv. Synth. Catal.2017, 359, 2773.

18.     “Aroyl chlorides as novel acyl radical precursors via visible-light photoredox catalysis”. Xu, S.-M.; Chen, J.-Q.; Liu, D.; Bao, Y.; Liang, Y.-M.;Xu, P.-F.*Org. Chem. Front.2017, 4, 1331.